Domestic and Foreign Product and Market Analysis of Polyimide Materials
PetroChina Company Limited, Petrochemical Research Institute, Beijing 102206, China
| Abstract: | Polyimide (PI) is one of the engineering plastics with excellent comprehensive properties. Currently, its preparation and application technology are closely related to a large number of cutting-edge technologies and products. Therefore, PI is listed in the category of key development materials in the ‘13th five-year plan’ of China. In te meantime, the production technology of high-performance PI is tightly controlled by a few international enterprises. On the other hand, PI related industries in China are established late and small in production scale, lacking the mastery of core technology, which make the production and application of PIs the "neck-clamping" technology, which needs to be developed urgently in China. In this paper, the classification and preparation methods of PI, as well as the development status and main product categories of PI manufacturers at home and abroad are summarized. It is explicit that foreign enterprises have rich PI product lines and wide product coverage, while China's PI industry has rich commodity products with overcapacity, but in shortage of high-end products. Essentially, although our industry has clear understanding of the PI synthetic fundamentals, the key-technical know-hows are leg behind and a large gap in production processes exists compared with the mature foreign producers. However, under the advantageous national policies guidance and supports, China's PI industry is now in a favorable developing environment and should be enjoying a rapid growth period. |
| Keywords: | Polyimide; Synthetic Process; Film; Fiber; Market |
| DOI: | 10.57237/j.mater.2022.02.001 |
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Received: 3 October 2022
Accepted: 15 November 2022
Published Online: 1 December 2022
Funding
| 1. | 国家自然科学基金委项目 (No. 22172024) |
References
| [1] | Wang W, Chengxiang L I, Zhang G, et al. Synthesis and Studies of Polyimide [J]. Materials Review, 2008-02. |
| [2] | Ni H J, Liu J G, Wang Z H, et al. A review on colorless and optically transparent polyimide films: Chemistry, process and engineering applications [J]. Journal of Industrial & Engineering Chemistry, 2015, 28: 16-27. |
| [3] | Doug, Wilson. Recent advances in polyimide composites [J] High Performance Polymers, 1993, 5 (2): 77-95. |
| [4] | Ma P, Dai C, Wang H, et al. A review on high temperature resistant polyimide films: Heterocyclic structures and nanocomposites [J]. Composites Communications, 2019, 16:84-93. |
| [5] | 屠强 沈惠丽, 3,3'-二甲基-4,4'-二氨基二苯甲烷型聚酰亚胺薄膜的研制 [C]. 第十届绝缘材料与绝缘技术学术会议. 北京: 中国电工技术学会，2008: 292-295. |
| [6] | 范琳, 陈建升, 胡爱军,等. 高性能聚酰亚胺材料的研究进展[J]. 材料工程, 2007(z1):160-163. |
| [7] | 佚名. "十三五"材料领域科技创新专项规划 [J]. 居业, 2017, 6: 9-16. |
| [8] | 杨小进, 陈文求, 易昌凤,等. 化学亚胺化和热亚胺化合成超支化聚酰亚胺 [J]. 高分子材料科学与工程, 2010, 26 (4): 25-28. |
| [9] | Jeong H J, Kobayashi A, Kakimoto M A, et al. Synthesis and Characterization of Novel Aromatic Polyimides from 3,4-Bis(4-aminophenyl)-2,5-diphenylthiophene and Aromatic Tetracarboxylic Dianhydrides [J]. Polymer Journal, 1994, 26 (3): 373-377. |
| [10] | Perry R J, Turner S R. Preparation of Polyimides Via the Palladium-Catalyzed Carbonylation and Condensation of Tetraiodoaromatics and Diamines [J]. Journal of Macromolecular Science: Part A - Chemistry, 1991, 28 (11-12): 1213-1223. |
| [11] | Perry R J, Wilson B D, Turner S R, et al. Synthesis of Polyimides via the Palladium-Catalyzed Carbonylation of Bis(o-iodo Esters) and Diamines [J]. Macromolecules 1995, 28, 10, 3509–3515. |
| [12] | Perry R J, Tunney S E, Wilson B D. Polyimide Formation through the Palladium-Mediated Carbonylation and Coupling of Bis(o-iodo amides) and Diamines [J] Macromolecules 1996, 29, 3, 1014–1020. |
| [13] | Kim J H, Moore J A. A low-temperature route to polyimides [J] Macromolecules 1993, 26, 14, 3510–3513. |
| [14] | Cotter R J, Sauers C K, Whelan J M. The Synthesis of N-Substituted Isomaleimides [J]. Journal of Organic Chemistry, 1961, 26 (1): 1847-1847. |
| [15] | Oishi Y, Kakimoto M, Imai Y. Synthesis of aromatic polyimides from N,N'-bis(trimethylsilyl)-substituted aromatic diamines and aromatic tetracarboxylic dianhydrides [J]. Macromolecules, 1991, 24 (12): 3475-3480. |
| [16] | Jackson R W, Manske R H. THE SYNTHESIS OF INDOLYL-BUTYRIC ACID AND SOME OF ITS DERIVATIVES [J]. Journal of the American Chemical Society, 2002, 52 (12): 5029-5035. |
| [17] | Jung J C, Park S B. Synthesis, characterization and properties of polyimides from 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and imidazole-blocked 2,5-bis[(n-alkyloxy)methyl]-1,4-benzenediisocyanates [J] Polymer Bulletin, 1995, 35(4):423-430. |
| [18] | Deibig V H, Plachky M. Thermostabile polymere III. Polyimide der 1,4‐benzohydrochinontetracarbonsre [J]. Die Angewandte Makromolekulare Chemie, 1973, 31 (1): 75–81. |
| [19] | Ghassemi H, Hay A S. Polyimides from N,N'-Diamino-1,4,5,8-naphthalenetetracarboxylic Bisimide [J] Macromolecules, 1994, 27 (11): 3116-3118. |
| [20] | Rogers M E, Glass T E, Mecham S J, et al. Perfectly alternating segmented polyimide-polydimethyl siloxane copolymers via transimidization [J] Journal of Polymer Science Part A:Polymer Chemistry, 1994, 32 (14): 2663-2675. |
| [21] | Freddy Helmer-Metzmann, Matthias Rehahn, Ludwig Schmitz, et al. A novel synthetic route to rigid-rod polyimides [J] Die Makromolekulare Chemie, 1992, 193 (8): 1847-1858. |
| [22] | Bailey W J, Economy J, Hermes M E. Polymers. IV. Polymeric Diels-Alder Reactions 1, 2 [J]. The Journal of Organic Chemistry, 1962, 27 (9): 3295-3299. |
| [23] | Kraiman E A. Maleimide polymers [P], US2890206, 1959. |
| [24] | Reeder J A. Polyimides from dimaleimides and bisfulvenes [P], US3334071, 1967. |
| [25] | Diakoumakos C D, Mikroyannidis J A. Heat-resistant resins derived from cyano-substituted Diels-Alder polymers [J]. European Polymer Journal, 1994, 30 (4): 465-472. |
| [26] | Diakoumakos C D, Mikroyannidis J A. Heat-resistant polyimides and polyamides prepared from 2, 7ヾiaminoicyanomethylene-fluorene [J]. Journal of Applied Polymer Science, 1994, 54 (13): 2063-2073. |
| [27] | Alhakimi G, Gorls H, Klemm E. Polyimides by Diels-Alder polyaddition of α-pyrones [J]. Macromolecular Chemistry and Physics, 1994, 195 (5): 1569-1576. |
| [28] | Romdhane H B, Baklouti M, Chaabouni M R, et al. Polypentamethylnadimides obtained by Diels–Alder reaction [J]. Polymer, 2002, 43 (2): 255-268. |
| [29] | 来育梅. 热塑性聚酰亚胺及其改性材料的热性能研究 [D]. 南京: 南京工业大学, 2006. |
| [30] | Hergenrother P M. The use, design, synthesis, and properties of high performance/high temperature polymers: An overview [J]. High Performance Polymers, 2003, 15 (1): 3-45. |
| [31] | 张建明. 可溶性聚酰亚胺的合成及性能研究 [D]. 上海: 上海交通大学, 1997. |
| [32] | 陈彦, 谢美丽. 醚酐型聚酰亚胺性能的研究 [J]. 高分子材料, 1992 (3): 18-21. |
| [33] | 丁孟贤. 聚酰亚胺-化学、结构与性能的关系及材料[M] .北京: 科学出版社, 2006. |
| [34] | 余彬, 蒋彩荣, 汪称意. 一类高透明含氟共聚型聚酰亚胺的合成与表征 [J]. 精细化工, 2019, 36 (12): 2406-2410, 2430. |
| [35] | 于卓. 溶液喷射法制备聚酰亚胺纳米纤维及其碳纳米纤维[D]. 天津: 天津工业大学, 2015. |
| [36] | 阎敬灵, 孟祥胜, 王震, 等. 热固性聚酰亚胺树脂研究进展[J]. 应用化学, 2015, 32 (5): 489-497. |
| [37] | 杨士勇, 高生强, 胡爱军,等. 耐高温聚酰亚胺树脂及其复合材料的研究进展[J]. 宇航材料工艺, 2000, 30(1):6. |
| [38] | 孙自淑, 江天, 马家举,等. 聚酰亚胺的改性及应用进展 [J]. 化工科技, 2005, 13 (5): 54-58. |
| [39] | 郭海泉. 高性能聚酰亚胺薄膜的市场需求与技术挑战 [J]. 覆铜板资讯, 2018 (5): 38-45. |
| [40] | 左琴平, 林红, 陈宇岳. 聚酰亚胺纤维的开发及应用进展[J]. 纺织导报, 2018 (5): 60-63. |
| [41] | 庞顺强. 聚酰亚胺泡沫材料在舰船上的应用 [J]. 材料开发与应用, 2001, 16 (3): 38-41. |
| [42] | Hedrick J L, Carter K R, Cha H J, et al. High-temperature polyimide nanofoams for microelectronic applications [J]. 1996, 30 (1-3): 43-53. |
| [43] | Xie J, Xin D, Cao H, et al. Improving carbon fiber adhesion to polyimide with atmospheric pressure plasma treatment[J]. Surface & Coatings Technology, 2011, 206 (2-3): 191-201. |
| [44] | 魏文康, 虞鑫海, 王凯,等. 光敏聚酰亚胺的研究与应用进展 [J]. 合成技术及应用, 2018, 33 (3): 23-26. |
| [45] | 潘晓娣, 戴钧明, 钱明球. 聚酰亚胺薄膜的国内外开发进展 [J]. 合成技术及应用, 2018, 33 (2): 22-28. |
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