College of Land Resources and Environment, Jiangxi Agricultural University, Nanchang 330045, China
| Abstract: | Research and development of water purification technology can effectively alleviate the impact of water shortage. Capacitive deionization technology (CDI) is a novel water treatment technology, by applying low voltage, ions in solution are absorbed by electrodes to form double electric layers to remove pollutants in water. Electrode material is the main factor affecting the effect of CDI treatment. At present, the traditional CDI electrodes mainly focus on the research of carbon materials and carbon-based composites materials. However, their low effective specific surface area, complex preparation process and high resistance limit their application in practical wastewater treatment. Mixed metal oxides have become a new hotspot in the research and application of CDI electrode materials due to their excellent electrochemical properties, such as high reactivity, large specific capacitance and strong conductivity. However, there are few articles on its research and application in CDI. Therefore, this paper reviews the latest research progress, existing problems and application development of mixed metal oxide electrodes and their composite electrodes in the context of the types of polymetallic oxides. |
| Keywords: | Capacitive Deionization; Electrode Materials; Multiple Metal Oxides; Desalination |
| DOI: | 10.57237/j.wjese.2023.02.003 |
| [1] | Ahmed M A, Tewari S. Capacitive deionization: Processes, materials and state of the technology [J]. Journal of Electroanalytical Chemistry, 2018, 813: 178-192. |
| [2] | 石凤英. 浅谈水资源的保护与利用 [J]. 山西农经, 2019, (23): 88. |
| [3] | Gao X, Omosebi A, Holubowitch N, et al. Capacitive deionization using alternating polarization: effect of surface charge on salt removal [J]. Electrochimica Acta, 2017, 233: 249-255. |
| [4] | 尹广军, 陈福明. 电容去离子研究进展 [J]. 水处理技术, 2003(02): 63-66. |
| [5] | Jia B, Zhang W. Preparation and application of electrodes in capacitive deionization (CDI): a state-of-art review [J]. Nanoscale research letters, 2016, 11(1): 1-25. |
| [6] | Xing W, Liang J, Tang W, et al. Versatile applications of capacitive deionization (CDI)-based technologies [J]. Desalination, 2020, 482: 114390. |
| [7] | 赵飞, 苑志华, 钟鹭斌, 等. 电容去离子技术及其电极材料研究进展 [J]. 水处理技术, 2016, 42(05): 38-44. |
| [8] | 贾雪茹, 胡程月, 王昭玉, 等. 电容去离子技术在水处理领域的研究进展 [J]. 四川化工, 2019, 22(04): 25-28. |
| [9] | Chen Z, Zhang H, Wu C, et al. A study of electrosorption selectivity of anions by activated carbon electrodes in capacitive deionization [J]. Desalination, 2015, 369: 46-50. |
| [10] | Kumar R, Gupta S S, Katiyar S, et al. Carbon aerogels through organo-inorganic co-assembly and their application in water desalination by capacitive deionization [J]. Carbon, 2016, 99: 375-383. |
| [11] | Bian Y, Liang P, Yang X, et al. Using activated carbon fiber separators to enhance the desalination rate of membrane capacitive deionization [J]. Desalination, 2016, 381: 95-99. |
| [12] | Wang S, Wang D Z, Ji L J, et al. Equilibrium and kinetic studies on the removal of NaCl from aqueous solutions by electrosorption on carbon nanotube electrodes [J]. Separation and Purification Technology, 2007, 58(1): 12-16. |
| [13] | Xu K, Liu Y, An Z, et al. The polymeric conformational effect on capacitive deionization performance of graphene oxide/polypyrrole composite electrode [J ]. Desalination, 2020, 486: 114407. |
| [14] | 朱胜, 盛建, 贾国栋, 等. 介孔碳纳米材料的制备与改性 [J]. 无机化学学报, 2022, 38(01): 1-13. |
| [15] | 黄宽, 唐浩, 刘丹阳, 等. 电容去离子技术综述(二): 电极材料 [J]. 环境工程, 2016, 34(S1): 89-100. |
| [16] | Ding Z, Xu X, Li Y, et al. Significantly improved stability of hybrid capacitive deionization using nickel hexacyanoferrate/reduced graphene oxide cathode at low voltage operation [J]. Desalination, 2019, 468: 114078. |
| [17] | 孙婧, 陆晓赟, 宋海欧, 等. 具有阴阳离子插入行为的电容去离子电极设计 [J]. 化学通报, 2021, 84(05): 402-410. |
| [18] | Zhang H, Zhang F, Wei Y, et al. Controllable design and preparation of hollow carbon-based nanotubes for asymmetric supercapacitors and capacitive deionization [J]. ACS Applied Materials & Interfaces, 2021, 13(18): 21217-21230. |
| [19] | Ai J, Li J, Li K, et al. Highly flexible, self-healable and conductive poly (vinyl alcohol)/Ti3C2Tx MXene film and it’s application in capacitive deionization [J]. Chemical Engineering Journal, 2021, 408: 127256. |
| [20] | 孙娜, 阚二姐, 诸葛炳森, 等. 电容去离子水处理技术综述报告 [J]. 广州化工, 2022, 50(10): 11-13. |
| [21] | 赵雨, 李含, 许海民, 等. 金属氧化物纳米复合材料用于污水除氟的研究进展 [J/OL]. 工业水处理: 1-11 [2022-09-18]. |
| [22] | 张家祺, 赵彦龙, 张岩, 等. 层状双金属氢氧化物的应用研究进展 [J]. 化学工程与装备, 2022(04): 207-209. |
| [23] | Ulibarri M A, Pavlovic I, Barriga C, et al. Adsorption of anionic species on hydrotalcite-like compounds: effect of interlayer anion and crystallinity [J]. Applied Clay Science, 2001, 18(1-2): 17-27. |
| [24] | 李会华. 模板电沉积法制备柔性电极材料及其在超级电容器中的应用 [D]. 南京邮电大学, 2017. |
| [25] | 董国涛, 王静, 葛烨, 等. 单金属氧化物电极研究现状 [J]. 广州化工, 2021, 49(17): 14-17. |
| [26] | Kate R S, Khalate S A, Deokate R J. Overview of nanostructured metal oxides and pure nickel oxide (NiO) electrodes for supercapacitors: A review [J]. Journal of Alloys and Compounds, 2018, 734: 89-111. |
| [27] | 吴任钊, 石璞, 李顺, 等. 纳米二氧化锰的制备及其电容性能 [J]. 包装学报, 2021, 13(03): 57-63. |
| [28] | Chen M, Ge Q, Qi M, et al. Cobalt oxides nanorods arrays as advanced electrode for high performance supercapacitor [J]. Surface and Coatings Technology, 2019, 360: 73-77. |
| [29] | Cai W, Yu J, Jaroniec M. Template-free synthesis of hierarchical spindle-like γ-Al2O3 materials and their adsorption affinity towards organic and inorganic pollutants in water [J]. Journal of Materials Chemistry, 2010, 20(22): 4587-4594. |
| [30] | Jeong Y, Fan M, Singh S, et al. Evaluation of iron oxide and aluminum oxide as potential arsenic (V) adsorbents [J]. Chemical Engineering and Processing-Process Intensification, 2007, 46(10): 1030-1039. |
| [31] | 张玮倩, 许秀玲, 周国伟. 二元及三元过渡金属氧化物的制备及其电化学应用研究进展 [J]. 材料导报, 2018, 32(21): 3731-3736. |
| [32] | Bai Z, Hu C, Liu H, et al. Selective adsorption of fluoride from drinking water using NiAl-layered metal oxide film electrode [J]. Journal of Colloid and Interface Science, 2019, 539: 146-151. |
| [33] | Xi W, Li H. The pseudo-capacitive deionization behaviour of CuAl-mixed metal oxides [J]. Environmental Science: Water Research & Technology, 2020, 6(2): 296-302. |
| [34] | Gorle P. Bimetallic Co-Al layered oxide for augmenting the performance of capacitive deionization [J]. SPAST Abstracts, 2021, 1(01). |
| [35] | 赵得先, 王百年, 江晓, 等. 镁铝层状双金属氧化物脱除溶液中Cr(Ⅵ) [J]. 化工技术与开发, 2020, 49(08): 56-61. |
| [36] | 卢玉灵, 李大玉, 张超. 微波水热合成三元金属氧化物的研究进展 [J]. 材料导报, 2020, 34(S2): 1168-1172. |
| [37] | Chen D, Wang Q, Wang R, et al. Ternary oxide nanostructured materials for supercapacitors: a review [J]. Journal of Materials Chemistry A, 2015, 3(19): 10158-10173. |
| [38] | Hai A, Alqassem B, Bharath G, et al. Cobalt and nickel ferrites based capacitive deionization electrode materials for water desalination applications [J]. Electrochimica Acta, 2020, 363: 137083. |
| [39] | Hu C, Dong J, Wang T, et al. Nitrate electro-sorption/reduction in capacitive deionization using a novel Pd/NiAl-layered metal oxide film electrode [J]. Chemical Engineering Journal, 2018, 335: 475-482. |
| [40] | Wang W, Liu Z, Zhang Z, et al. Highly Efficient Capacitive Deionization Enabled by NiCo4MnO8. 5 Electrode s [J]. Global Challenges, 2022, 6(2): 2100095. |
| [41] | Shang X, Hu B, Nie P, et al. LiNi0. 5Mn1. 5O4-based hybrid capacitive deionization for highly selective adsorption of lithium from brine [J]. Separation and Purification Technology, 2021, 258: 118009. |
| [42] | Wang G, Li D, Wang S, et al. Ternary NiFeMn layered metal oxide (LDO) compounds for capacitive deionization defluoridation: the unique role of Mn [J]. Separation and Purification Technology, 2021, 254: 117667. |
| [43] | Hu C, Wang T, Dong J, et al. Capacitive deionization from reconstruction of NiCoAl-mixed metal oxide film electrode based on the “memory effect” [J]. Applied Surface Science, 2018, 459: 767-773. |
| [44] | 喻舰, 胡绅, 张须媚, 等. 提升电容去离子效能的电极材料功能化策略 [J]. 工业水处理, 2021, 41(11): 32-39. |
| [45] | El-Deen A G, Barakat N A M, Kim H Y. Graphene wrapped MnO2-nanostructures as effective and stable electrode materials for capacitive deionization desalination technology [J]. Desalination, 2014, 344: 289-298. |
| [46] | He Y, Chen W, Li X, et al. Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes [J]. ACS nano, 2013, 7(1): 174-182. |
| [47] | Liu Y, Xu X, Lu T, et al. Nitrogen-doped electrospun reduced graphene oxide–carbon nanofiber composite for capacitive deionization [J]. Rsc Advances, 2015, 5(43): 34117-34124. |
| [48] | Yasin A S, Mohamed H O, Mohamed I M A, et al. Enhanced desalination performance of capacitive deionization using zirconium oxide nanoparticles-doped graphene oxide as a novel and effective electrode [J]. Separation and Purification Technology, 2016, 171: 34-43. |
| [49] | Ren Q, Wang G, Wu T, et al. Calcined MgAl-layered double hydroxide/graphene hybrids for capacitive deionization [J]. Industrial & Engineering Chemistry Research, 2018, 57(18): 6417-6425. |
| [50] | Divyapriya G, Vijayakumar K K, Nambi I. Development of a novel graphene/Co3O4 composite for hybrid capacitive deionization system [J]. Desalination, 2019, 451: 102-110. |
| [51] | Younes H, Ravaux F, El Hadri N, et al. Nanostructuring of pseudocapacitive MnFe2O4/Porous rGO electrodes in capacitive deionization [J]. Electrochimica Acta, 2019, 306: 1-8. |
| [52] | Yousef A, Al-Enizi A M, Mohamed I M A, et al. Synthesis and characterization of CeO2/rGO nanoflakes as electrode material for capacitive deionization technology [J]. Ceramics International, 2020, 46(10): 15034-15043. |
| [53] | Yasin A S, hyun Kim D, Lee K. One-pot synthesis of activated carbon decorated with ZnO nanoparticles for capacitive deionization application [J]. Journal of Alloys and Compounds, 2021, 870: 159422. |
| [54] | Hussain T, Wang Y, Xiong Z, et al. Fabrication of electrospun trace NiO-doped hierarchical porous carbon nanofiber electrode for capacitive deionization [J]. Journal of colloid and interface science, 2018, 532: 343-351. |
| [55] | Angeles A T, Park J, Ham K, et al. High-performance capacitive deionization electrodes through regulated electrodeposition of manganese oxide and nickel-manganese oxide/hydroxide onto activated carbon [J]. Separation and Purification Technology, 2022, 280: 119873. |
| [56] | Feng J, Xiong S, Ren L, et al. Atomic layer deposition of TiO2 on carbon-nanotubes membrane for capacitive deionization removal of chromium from water [J]. Chinese Journal of Chemical Engineering, 2022, 45: 15-21. |
We invite active, qualified and high profile scientists and researchers to join as Editorial Board Members.
Join UsScholars with a strong interest in reviewing are invited to join the reviewer panel to ensure the quality of the research to be published.
Join Us