1. 西安石油大油气科技有限公司, 陕西西安 710000
2. 西安长庆化工集团有限公司, 陕西西安 710000
3. 西安石油大学, 陕西省油气田环境污染控制技术与储层保护重点实验室, 陕西西安 710000
| 摘 要: | 随着全球人口数量的不断增加,社会经济的不断发展,全球对石油资源的年度需求大幅度增加。根据调查结果显示,稠油资源非常丰富,约占全球石油总储量的70%左右,远大于传统原油,因此,稠油的开采尤为重要。由于常规石油供应有限和石油需求飙升,中国的石油安全将面临前所未有的挑战。水热裂解工艺是全球成功开采稠油的关键且是经济的降粘技术之一。本文简要介绍了中国稠油资源概况、稠油开采的技术手段和储层原位稠油水热裂解技术的发展,并详细介绍了水热裂解催化剂的分类和水热裂解降粘机理的研究。最适合的催化剂均含有强活性位点,这些位点可以破坏稠油中胶质和沥青质的杂原子键,促使饱和烃和芳香烃含量的增加。最后对目前稠油水热裂解技术存在的问题及今后的发展趋势进行了分析。 |
| 关 键 词: | 稠油; 水热裂解; 催化剂; 降粘 |
| DOI: | 10.57237/j.cse.2024.01.002 |
1. Xi'an Petroleum Technology Co. Ltd, Xi’an 710000, China
2. Xi’an Changqing Chemical Group Co. Ltd, Xi’an 710000, China
3. Shaanxi Province Key Laboratory of Environmental Pollution Control and Reservoir Protection Technology of Oilfields, Xi’an Petroleum University, Xi’an 710000, China
| Abstract: | With the continuous increase of the global population and the continuous development of the social economy, the annual global demand for oil resources has increased significantly. According to the survey results, heavy oil resources are very rich, accounting for about 70% of the world's total oil reserves, much larger than traditional crude oil, so the exploitation of heavy oil is particularly important. Due to the limited supply of conventional oil and soaring oil demand, China's oil security will face unprecedented challenges. Aquathermolysis process is one of the key and economical viscosity reduction technologies for successful recovery of heavy oil in the world. This paper briefly introduces the overview of heavy oil resources in China, the technical means of heavy oil exploitation and the development of heavy oil aquathermolysis technology, and introduces in detail the classification of aquathermolysis catalysts and the research on viscosity reduction mechanism of aquathermolysis. The most suitable catalysts contain strong active sites, which can break the heteroatomic bonds of resin and asphaltene in heavy oil and promote the increase of saturated hydrocarbon and aromatic hydrocarbon content. Finally, the problems and future development trends of heavy oil aquathermolysis technology are analyzed. |
| Keywords: | Heavy Oil; Aquathermolysis; Catalysts; Viscosity Reduction |
| 1. | 国家自然科学基金项目“内外源超分子协同催化稠油原位改质新策略” (51974252) |
| [1] | 徐金华. N1区J层剩余油及开发调整研究 [D]. 青岛: 中国石油大学 (华东), 2017. |
| [2] | Iskandar F, Dwinanto E, Abdullah M, et al. Viscosity reduction of heavy oil using nanocatalyst in aquathermolysis reaction [J]. KONA Powder and Particle Journal, 2016, 33: 3-16. |
| [3] | Jia CZ, Zheng M, Zhang YF. Unconventional hydrocarbon resources in China and the prospect of exploration and development [J]. Petroleum Exploration and Development, 2012, 39(2): 139-146. |
| [4] | Lv S, Peng S, Zhang R, et al. Viscosity reduction of heavy oil by ultrasonic [J]. Petroleum Chemistry, 2020, 60(9): 998-1002. |
| [5] | Zhang J, Guo Z, Du W, et al. Preparation and performance of vegetable oils fatty acids hydroxylmethyl triamides as crude oil flow improvers [J]. Petroleum Chemistry, 2018, 58: 1070-1075. |
| [6] | Muraza O, Galadima A. Aquathermolysis of heavy oil: A review and perspective on catalyst development [J]. Fuel, 2015, 157: 219-231. |
| [7] | Huang S, Cao M, Huang Q, et al. Study on reaction equations of heavy oil aquathermolysis with superheated steam [J]. International Journal of Environmental Science and Technology, 2019, 16: 5023-5032. |
| [8] | Zhao D W, Wang J, Gates I D. Thermal recovery strategies for thin heavy oil reservoirs [J]. Fuel, 2014, 117: 431-441. |
| [9] | Li C, Huang W, Zhou C, et al. Advances on the transition-metal based catalysts for aquathermolysis upgrading of heavy crude oil [J]. Fuel, 2019, 257: 115779. |
| [10] | Maity S K, Ancheyta J, Marroquín G. Catalytic aquathermolysis used for viscosity reduction of heavy crude oils: A review [J]. Energy & Fuels, 2010, 24(5): 2809-2816. |
| [11] | Almao P P. In situ upgrading of bitumen and heavy oils via nanocatalysis [J]. The Canadian Journal of Chemical Engineering, 2012, 90(2): 320-329. |
| [12] | Speight J G. The chemistry and technology of petroleum. Marcel Dekker [J]. Inc. New York, 1980. |
| [13] | Yang Y, Wang X, Wang T. China’s Heavy-Oil Development Technology: Status and Recommendations [J]. Open Journal of Nature Science, 2019, 7(6): 471-477. |
| [14] | 张贵才, 潘斌林, 葛际江, 等. 稠油蒸汽吞吐热裂解行为研究 [J]. 西安石油大学学报(自然科学版), 2006(5): 46-49+92. |
| [15] | Strausz O P, Mojelsky T W, Payzant J D, et al. Upgrading of Alberta's heavy oils by superacid-catalyzed hydrocracking [J]. Energy & Fuels, 1999, 13(3): 558-569. |
| [16] | Clark P D, Hyne J B. Studies on the chemical reactions of heavy oils under steam stimulation condition [J]. Aostra J Res, 1990, 6(1): 29-39. |
| [17] | Hongfu F, Yongjian L, Liying Z, et al. The study on composition changes of heavy oils during steam stimulation processes [J]. Fuel, 2002, 81(13): 1733-1738. |
| [18] | Fan H, Zhang Y, Lin Y. The catalytic effects of minerals on aquathermolysis of heavy oils [J]. Fuel, 2004, 83(14-15): 2035-2039. |
| [19] | Zhong L G, Liu Y J, Fan H F, et al. Liaohe extra-heavy crude oil underground aquathermolytic treatments using catalyst and hydrogen donors under steam injection conditions [C]//SPE international improved oil recovery conference in Asia Pacific. OnePetro, 2003. |
| [20] | Jie Z, Xiao-long L I, Gang C, et al. Study on aquathermolysis of heavy oil at relatively low temperature catalyzed by water-soluble complexes [J]. 燃料化学学报, 2014, 42(04): 443-448. |
| [21] | Zhao F, Liu Y, Fu Z, et al. Using hydrogen donor with oil-soluble catalysts for upgrading heavy oil [J]. Russian Journal of Applied Chemistry, 2014, 87: 1498-1506. |
| [22] | Zhao X, Tan X, Liu Y. Behaviors of oil-soluble catalyst for aquathermolysis of heavy oil [J]. Ind Catal, 2008, 11: 31-4. |
| [23] | Zhao F, Wang X, Wang Y, et al. The catalytic aquathermolysis of heavy oil in the presence of a hydrogen donor under reservoirs conditions [J]. Journal of Chemical and Pharmaceutical Research, 2014, 6(5): 2037-2041. |
| [24] | Chao K, Chen Y, Li J, et al. Upgrading and visbreaking of super‐heavy oil by catalytic aquathermolysis with aromatic sulfonic copper [J]. Fuel Processing Technology, 2012, 104: 174-180. |
| [25] | Li J, Chen Y, Liu H, et al. Influences on the aquathermolysis of heavy oil catalyzed by two different catalytic ions: Cu2+ and Fe3+ [J]. Energy & fuels, 2013, 27(5): 2555-2562. |
| [26] | Suwaid M A, Varfolomeev M A, Al-Muntaser A A, et al. In-situ catalytic upgrading of heavy oil using oil-soluble transition metal-based catalysts [J]. Fuel, 2020, 281: 118753. |
| [27] | Chen G, Zhou Z, Shi X, et al. Synthesis of alkylbenzenesulfonate and its behavior as flow improver in crude oil [J]. Fuel, 2021, 288: 119644. |
| [28] | Clark P D, Hyne J B, Tyrer J D. Chemistry of organosulphur compound types occurring in heavy oil sands: 1. High temperature hydrolysis and thermolysis of tetrahydrothiophene in relation to steam stimulation processes [J]. Fuel, 1983, 62(8): 959-962. |
| [29] | Ovalles C, Vallejos C, Vasquez T, et al. Downhole upgrading of extra-heavy crude oil using hydrogen donors and methane under steam injection conditions [J]. Petroleum science and technology, 2003, 21(1-2): 255-274. |
| [30] | 张弦, 刘永健, 范英才. 辽河稠油水热裂解催化及化学强化降黏研究 [J]. 特种油气藏, 2017, 18(2): 99-101. |
| [31] | Lu G. Catalytic properties of SO42− Ti-MO superacids in esterification [J]. Applied Catalysis A: General, 1995, 133(1): 11-18. |
| [32] | Wang H, Wu Y, He L, et al. Supporting tungsten oxide on zirconia by hydrothermal and impregnation methods and its use as a catalyst to reduce the viscosity of heavy crude oil [J]. Energy & fuels, 2012, 26(11): 6518-6527. |
| [33] | 闻守斌, 刘永建, 宋玉旺, 等. 硅钨酸对胜利油田超稠油的催化降黏作用 [J]. 大庆石油学院学报, 2016, 28(1): 25-27. |
| [34] | Jing P, Li Q, Han M, et al. Visbreaking of heavy petroleum oil catalyzed by SO42−/ZrO2 solid super-acid doped with Ni2+ or Sn2+ [J]. Frontiers of Chemical Engineering in China, 2008, 2: 186-190. |
| [35] | FAN Z, WANG T, HE Y. Upgrading and viscosity reducing of heavy oils by [BMIM] [AlCl4] ionic liquid [J]. Journal of Fuel Chemistry and Technology, 2009, 37(6): 690-693. |
| [36] | Subramanian D, Wu K, Firoozabadi A. Ionic liquids as viscosity modifiers for heavy and extra-heavy crude oils [J]. Fuel, 2015, 143: 519-526. |
| [37] | Zou C J, Liu C, Huang Z Y, et al. Catalytic degradation of macromolecular constituents of asphaltic sands in ionic liquids [J]. Journal of Industrial and Engineering Chemistry, 2019, 55(12): 2095-2098. |
| [38] | Monin J C, Audibert A. Thermal cracking of heavy oil/mineral matrix systems [C]//SPE international symposium on oilfield chemistry. OnePetro, 1987. |
| [39] | Zhou Z, Slaný M, Kuzielová E, et al. Influence of reservoir minerals and ethanol on catalytic aquathermolysis of heavy oil [J]. Fuel, 2022, 307: 121871. |
| [40] | Ma L, Zhang S, Zhang X, et al. Enhanced aquathermolysis of heavy oil catalysed by bentonite supported Fe (III) complex in the present of ethanol [J]. Journal of Chemical Technology & Biotechnology, 2022, 97(5): 1128-1137. |
| [41] | Aliev F A, Kiekbaev A A, Andreev D V, et al. The Effect of Clay Minerals on Conversion of Yarega Heavy Oil During Catalytic Aquathermolysis Processes [J]. SOCAR Proc, 2021, 2: 41-47. |
| [42] | Speight J G. Petroleum Asphaltenes-Part 1: Asphaltenes, resins and the structure of petroleum [J]. Oil & gas science and technology, 2004, 59(5): 467-477. |
| [43] | Timko M T, Ghoniem A F, Green W H. Upgrading and desulfurization of heavy oils by supercritical water [J]. The Journal of Supercritical Fluids, 2015, 96: 114-123. |
| [44] | 王行信, 蔡进功, 包于进. 粘土矿物对有机质生烃的催化作用 [J]. 海相油气地质, 2006, 11(3): 27-38. |
| [45] | Arcelus-Arrillaga P, Pinilla J L, Hellgardt K, et al. Application of water in hydrothermal conditions for upgrading heavy oils: a review [J]. Energy & Fuels, 2017, 31(5): 4571-4587. |
| [46] | Cuijpers M C M, Boot M D, Deen N G, et al. Sulphur and viscosity reductions in heavy hydrocarbons by subcritical water processing [J]. Journal of Petroleum Science and Engineering, 2019, 172: 1069-1076. |
| [47] | Eletskii P M, Sosnin G A, Zaikina O O, et al. Heavy oil upgrading in the presence of water [J]. Journal of Siberian Federal University. Chemistry, 2017, 10(4): 545-572. |
| [48] | Gai X K, Arano H, Lu P, et al. Catalytic bitumen cracking in sub-and supercritical water [J]. Fuel Processing Technology, 2016, 142: 315-318. |
| [49] | Hosseinpour M, Fatemi S, Ahmadi S J, et al. The synergistic effect between supercritical water and redox properties of iron oxide nanoparticles during in-situ catalytic upgrading of heavy oil with formic acid. Isotopic study [J]. Applied Catalysis B: Environmental, 2018, 230: 91-101. |
| [50] | Tan X C, Zhu C C, Liu Q K, et al. Co-pyrolysis of heavy oil and low density polyethylene in the presence of supercritical water: The suppression of coke formation [J]. Fuel processing technology, 2014, 118: 49-54. |
| [51] | 王元庆. 低温稠油水热裂解催化降粘研究 [D]. 武汉: 中国地质大学, 2010. |
| [52] | 杨博, 蔡忠贤, 赵文光. 不同粘土矿物对干酪根生烃的催化作用 [J]. 重庆科技学院学报(自然科学版), 2009, 11(1): 68-71. |
| [53] | 范洪富. 辽河稠油水热裂解反应研究与应用 [D]. 大庆: 大庆石油学院, 2002. |
| [54] | Fan H F, Liu Y J, Zhong L G. Studies on the synergetic effects of mineral and steam on the composition changes of heavy oils [J]. Energy & Fuels, 2001, 15(6): 1475-1479. |
| [55] | 李云峰, 钱会. 蒸汽吞吐稠油储层矿物溶蚀量和沉淀量的计算 [J]. 油田化学, 1997, 14(02): 48-52. |
| [56] | 庞河清, 曾焱, 刘成川, 等. 川西坳陷须五段储层微观孔隙结构特征及其控制因素 [J]. 中国石油勘探, 2017, 22(04): 48-60. |
| [57] | Goldstein T P. Geocatalytic reactions in formation and maturation of petroleum [J]. AAPG Bulletin, 1983, 67(1): 152-159. |
| [58] | 马向贤, 郑建京, 王晓锋, 等. 黏土矿物对油气生成的催化作用: 研究进展与方向 [J]. 岩性油气藏, 2015, 27(02): 55-61+69. |
| [59] | Kayukova G P, Mikhailova A N, Kosachev I P, et al. Catalytic hydrothermal conversion of heavy oil in the porous media [J]. Energy & Fuels, 2021, 35(2): 1297-1307. |
| [60] | Zhao F, Liu Y, Lu N, et al. A review on upgrading and viscosity reduction of heavy oil and bitumen by underground catalytic cracking [J]. Energy Reports, 2021, 7: 4249-4272. |
| [61] | Zhang X, Ying F, Yong L, et al. Effects of reservoir minerals and chemical agents on aquathermolysis of heavy oil during steam injection [J]. China Petroleum Processing & Petrochemical Technology, 2010, 12(3): 25. |