Co-Ni Bimetallic Sulfides Functionalized Interlayer with Efficient Catalytic Conversion for Li-S Batteries
Guangxi Key Laboratory of Low Carbon Energy Materials, Guangxi New Energy Ship Battery Engineering Technology Research Center, Guangxi Scientific, and Technological Achievements Transformation Pilot Research Base of Electrochemical Energy Materials and Devices, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China
| Abstract: | Tardive practical development of lithium-sulfur (Li-S) batteries faces two fatal nuisances, the grievous shuttle effect of sulfur electrodes as well as rock-ribbed Li dendrites, which results in undesired cycling lifespan and the potential safety hazard. Diversified electrocatalytic materials are employed to enhance polysulfides conversion kinetics and subsequently restrain shuttle effect. Here, pyrite-type cation regulation strategy is applied to motivate the electrochemical catalysis capability of bimetallic sulfide by regulating the cation ratio of Co and Ni ions. The reformative bimetallic sulfide with Co to Ni ratio near 2:1 shows stronger chemical adsorption capability towards lithium polysulfides in contrast to pristine NiS2, which resulted from the strong contribution of metal oxide layer. The comparable electrochemical kinetics and electrochemical performances of Li-S batteries with CNS-2/CP interlayer show in the aspects of low polarization voltage, high lithium ion diffusion rate, high discharge capacity, as well as better rate performances. These results demonstrate cation regulation could be an efficient strategy for material design to optimize the surface physicochemical properties of iron pyrite for boosting the cycle durability of Li-S batteries. |
| Keywords: | Li-S Batteries; Lithium Polysulfides; Catalytic Conversion; Functionalized Interlayer; Bimetallic Sulfide |
| DOI: | 10.57237/j.jest.2023.02.001 |
View:
Downloads:
收稿日期: 2022-10-28
接受日期: 2023-03-07
在线出版日期: 2023-03-28
基金
| 1. | National Natural Science Foundation of China (22002025) |
| 2. | Guangxi Natural Science Foundation (2021GXNSFAA075040, 2021GXNSFBA220078) |
| 3. | Guangxi Technology Base and Talent Subject (GUIKE AD18126001, GUIKE AD19110119, GUIKE AD19110028) |
参考文献
| [1] | H. J. Zhou, C. L. Song, L. P. Si, X. J. Hong and Y. P. Cai, Catalysts, 2020, 10, 9524-9532. |
| [2] | S. Huang, E. Huixiang, Y. Yang, Y. Zhang, M. Ye and C. C. Li, Journal of Materials Chemistry A, 2021, 9, 7458-7480. |
| [3] | L. Zhou, D. L. Danilov, R.-A. Eichel and P. H. L. Notten, Advanced Energy Materials, 2020, 11, 2001304. |
| [4] | M. Zhao, B.-Q. Li, X.-Q. Zhang, J.-Q. Huang and Q. Zhang, ACS Central Science, 2020, 6, 1095-1104. |
| [5] | C. Zhao, G.-L. Xu, T. Zhao and K. Amine, Angewandte Chemie International Edition, 2020, 59, 17634-17640. |
| [6] | H. Shin, M. Baek, A. Gupta, K. Char, A. Manthiram and J. W. Choi, Advanced Energy Materials, 2020, 10, 2001456. |
| [7] | M. Asif, Z. Ali, H. Qiu, M. Rashad and Y. Hou, ACS Applied Energy Materials, 2020, 3, 3541-3552. |
| [8] | S. Nanda and A. Manthiram, Energy & Environmental Science, 2020, 13, 2501-2514. |
| [9] | W. G. Lim, S. Kim, C. Jo and J. Lee, Angewandte Chemie, 2019, 58, 18746-18757. |
| [10] | S. J. Kim, K. Kim, J. Park and Y. E. Sung, ChemCatChem, 2019, 11, 2373-2387. |
| [11] | D. Liu, C. Zhang, G. Zhou, W. Lv, G. Ling, L. Zhi and Q. H. Yang, Advanced science, 2018, 5, 1700270. |
| [12] | D. Liu, X. Zhang, Y.-J. Wang, S. Song, L. Cui, H. Fan, X. Qiao and B. Fang, Nanoscale, 2020, 12, 9524-9532. |
| [13] | M. Rana, B. Luo, M. R. Kaiser, I. Gentle and R. Knibbe, Journal of Energy Chemistry, 2020, 42, 195-209. |
| [14] | Q. Pang, X. Liang, C. Y. Kwok and L. F. Nazar, Nature Energy, 2016, 1, 16132. |
| [15] | P. Li, Z. Zhuang, C. Du, D. Xiang, F. Zheng, Z. Zhang, Z. Fang, J. Guo, S. Zhu and W. Chen, ACS applied materials & interfaces, 2020, 12, 40194-40203. |
| [16] | K. Liang, K. Marcus, S. Zhang, L. Zhou, Y. Li, S. T. De Oliveira, N. Orlovskaya, Y.-H. Sohn and Y. Yang, Advanced Energy Materials, 2017, 7, 1701309. |
| [17] | J. Liu, S. H. Xiao, Z. Zhang, Y. Chen, Y. Xiang, X. Liu, J. S. Chen and P. Chen, Nanoscale, 2020, 12, 5114-5124. |
| [18] | S. L. Li, W. F. Zhang, J. F. Zheng, M. Y. Lv, H. Y. Song and L. Du, Advanced Energy Materials, 2021, 11, 2000779. |
| [19] | Y. Huang, D. Lv, Z. Zhang, Y. Ding, F. Lai, Q. Wu, H. Wang, Q. Li, Y. Cai and Z. Ma, Chemical Engineering Journal, 2020, 387, 124122. |
| [20] | D. Zheng, X.-Q. Yang and D. Qu, ChemSusChem, 2016, 9, 2348-2350. |
| [21] | D. Luo, Z. Zhang, G. Li, S. Cheng, S. Li, J. Li, R. Gao, M. Li, S. Sy, Y.-P. Deng, Y. Jiang, Y. Zhu, H. Dou, Y. Hu, A. Yu and Z. Chen, ACS nano, 2020, 14, 4849-4860. |
| [22] | J. He, Y. Chen and A. Manthiram, Advanced Energy Materials, 2019, 9, 1900584. |
| [23] | S.-H. Chung and A. Manthiram, Advanced Functional Materials, 2014, 24, 5299-5306. |
| [24] | P. Han and A. Manthiram, Journal of Power Sources, 2017, 369, 87-94. |
| [25] | J. Zhou, X. Liu, J. Zhou, H. Zhao, N. Lin, L. Zhu, Y. Zhu, G. Wang and Y. Qian, Nanoscale Horizons, 2019, 4, 182-189. |
| [26] | C. Li, M. Liu, H. Ding, L. He, E. Wang, B. Wang, S. Fan and K. Liu, Journal of Materials Chemistry A, 2020, 8, 17527-17536. |
| [27] | X. Yao, H. Cheng, Z. Jiang, Q. Han, Y. Wang and S. Wang, New Journal of Chemistry, 2020, 44, 10404-10409. |
| [28] | W. Du, Z. Wang, Z. Zhu, S. Hu, X. Zhu, Y. Shi, H. Pang and X. Qian, Journal of Materials Chemistry A, 2014, 2, 9613-9619. |
| [29] | Z. Gao, C. Chen, J. Chang, L. Chen, P. Wang, D. Wu, F. Xu, Y. Guo and K. Jiang, Electrochimica Acta, 2018, 281, 394-404. |
| [30] | Q. Wang, F. Gao, B. Xu, F. Cai, F. Zhan, F. Gao and Q. Wang, Chemical Engineering Journal, 2017, 327, 387-396. |
| [31] | D. Han, J. Wei, Y. Zhao, Y. Shen, Y. Pan, Y. Wei and L. Mao, Inorganic Chemistry Frontiers, 2020, 7, 1428-1436. |
| [32] | C. Liu, H. Ma, M. Yuan, Z. Yu, J. Li, K. Shi, Z. Liang, Y. Yang, T. Zhu, G. Sun, H. Li and S. Ma, Electrochimica Acta, 2018, 286, 195-204. |
| [33] | Y. J. Li, S. Y. Lin, D. D. Wang, T. T. Gao, J. W. Song, P. Zhou, Z. K. Xu, Z. H. Yang, N. Xiao and S. J. Guo, Advanced materials, 2020, 32, 10. |
| [34] | Z. Shan, Y. He, N. Liu, J. Li, M. Li and Y. Zhang, Applied Surface Science, 2021, 539, 148209. |
| [35] | W. Qiu, J. Li, Y. Zhang, G. Kalimuldina and Z. Bakenov, Nanotechnology, 2021, 32, 075403. |
| [36] | J. Li, Y. Chen, S. Zhang, W. Xie, S.-M. Xu, G. Wang and M. Shao, ACS applied materials & interfaces, 2020, 12, 49519-49529. |
| [37] | J. W. Guo and M. S. Wu, Electrochimica Acta, 2019, 327, 10. |
| [38] | W. Ren, L. Xu, L. Zhu, X. Wang, X. Ma and D. Wang, ACS applied materials & interfaces, 2018, 10, 11642-11651. |
| [39] | Z. Sun, X. L. Wu, Z. Peng, J. Wang, S. Gan, Y. Zhang, D. Han and L. Niu, Small, 2019, 15, e1902491. |
| [40] | J. Xu, W. Zhang, H. Fan, F. Cheng, D. Su and G. Wang, Nano Energy, 2018, 51, 73-82. |
| [41] | Y. Men, P. Li, F. Yang, G. Cheng, S. Chen and W. Luo, Applied Catalysis B: Environmental, 2019, 253, 21-27. |
| [42] | F. Ma, X. Wang, J. Wang, Y. Tian, J. Liang, Y. Fan, L. Wang, T. Wang, R. Cao, S. Jiao, J. Han, Y. Huang and Q. Li, Electrochimica Acta, 2020, 330, 135310. |
| [43] | Q. Yuan, Y. Chen, A. Li, Y. Li, X. Chen, M. Jia and H. Song, Applied Surface Science, 2020, 508, 145286. |
| [44] | X. Liao, Z. Li, Q. He, L. Xia, Y. Li, S. Zhu, M. Wang, H. Wang, X. Xu, L. Mai and Y. Zhao, ACS applied materials & interfaces, 2020, 12, 9181-9189. |
| [45] | B. Liu, S. Huang, D. Kong, J. Hu and H. Y. Yang, Journal of Materials Chemistry A, 2019, 7, 7604-7613. |
| [46] | B. Guo, S. Bandaru, C. Dai, H. Chen, Y. Zhang, Q. Xu, S. Bao, M. Chen and M. Xu, ACS applied materials & interfaces, 2018, 10, 43707-43715. |
| [47] | J. Duan, Y. Zou, Z. Li, B. Long and Y. Du, J. Electroanal. Chem., 2019, 847, 113187. |
| [48] | X. Tan, X. Wang, X. Wang, Y. Wang, C. Li and D. Xia, Ionics, 2019, 25, 4047-4056. |
| [49] | Z. Li, Z. Ma, Y. Wang, R. Chen, Z. Wu and S. Wang, Science Bulletin, 2018, 63, 169-175. |
| [50] | C. Yang, X. Wang, G. Liu, W. Yu, X. Dong and J. Wang, Journal of Colloid and Interface Science, 2020, 565, 378-387. |
| [51] | Y.-T. Liu, D.-D. Han, L. Wang, G.-R. Li, S. Liu and X.-P. Gao, Advanced Energy Materials, 2019, 9, 1803477. |
| [52] | Z. Shen, M. Cao, Z. Zhang, J. Pu, C. Zhong, J. Li, H. Ma, F. Li, J. Zhu, F. Pan and H. Zhang, Advanced Functional Materials, 2020, 30, 1906661. |
| [53] | M. Zhao, H.-J. Peng, Z.-W. Zhang, B.-Q. Li, X. Chen, J. Xie, X. Chen, J.-Y. Wei, Q. Zhang and J.-Q. Huang, Angewandte Chemie International Edition, 2019, 58, 3779-3783. |
| [54] | L. Zhang, Z. Chen, N. Dongfang, M. Li, C. Diao, Q. Wu, X. Chi, P. Jiang, Z. Zhao, L. Dong, R. Che, K. P. Loh and H. Lu, Advanced Energy Materials, 2018, 8, 1802431. |
| [55] | J. Zhang, Z. Li, Y. Chen, S. Gao and X. W. Lou, Angewandte Chemie International Edition, 2018, 57, 10944-10948. |
| [56] | J.-Y. Hwang, H. M. Kim, S. Shin and Y.-K. Sun, Advanced Functional Materials, 2018, 28, 1704294. |
| [57] | X. Li, G. Guo, N. Qin, Z. Deng, Z. Lu, D. Shen, X. Zhao, Y. Li, B.-L. Su and H.-E. Wang, Nanoscale, 2018, 10, 15505-15512. |
| [58] | C. Y. Zhang, Z. W. Lu, Y. H. Wang, Z. Dai, H. Zhao, G. Z. Sun, W. Lan, X. J. Pan, J. Y. Zhou and E. Q. Xie, Chemical Engineering Journal, 2020, 392, 123734. |
| [59] | S. Huang, Y. Wang, J. Hu, Y. Von Lim, D. Kong, L. Guo, Z. Kou, Y. Chen and H. Y. Yang, NPG Asia Materials, 2019, 11, 55. |
| [60] | S. Chen, Z. Wu, J. Luo, X. Han, J. Wang, Q. Deng, Z. Zeng and S. Deng, Electrochimica Acta, 2019, 312, 109-118. |
| [61] | Z. W. Seh, Y. Sun, Q. Zhang and Y. Cui, Chemical Society reviews, 2016, 45, 5605-5634. |
