GMA改性纤维素气凝胶的应用进展
1. 佳化化学科技发展（上海）有限公司, 上海 200120
2. 上海工程技术大学, 化学化工学院, 上海 201620
| 摘 要： | 纤维素气凝胶因其具有的密度低、孔隙率高、导热系数低等特点在众多改性复合材料中崭露头角，备受人们的关注。甲基丙烯酸缩水甘油酯(GMA)作为近年来涌现的一种成本低、毒性小、生物相容性好、易化学改性的新型聚合单体，广泛应用于橡胶、纤维及其他高分子材料的改性。以甲基丙烯酸缩水甘油作为桥梁连接其他材料构建的纤维素复合气凝胶具有丰富的功能性，在生物医药、催化、吸附等领域展现了巨大的应用潜力。本文首先简要阐述气凝胶及纤维素的分类和性能，随后介绍了纤维素气凝胶的合成方法，并综述了近年来甲基丙烯酸缩水甘油酯改性纤维素合成复合气凝胶在各领域的使用。本文分别概述了GMA改性纤维素复合气凝胶在重金属和染料的吸附领域的应用，以及作为生物组织、伤口敷料、药物载体、生物传感器、催化载体的应用。最后本文对GMA改性纤维素气凝胶未来的发展前景以及当前局限做了简要介绍。 |
| 关 键 词： | 纤维素; 气凝胶; 甲基丙烯酸缩水甘油酯; 应用 |
| DOI： | 10.57237/j.se.2023.03.001 |
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收稿日期: 2022-09-24
接受日期: 2022-10-26
在线出版日期: 2023-04-25
Application Progress of Cellulose Aerogel Modified by GMA
1. Jiahua Science & Technology Development (Shanghai) Ltd, Shanghai 200120, China
2. School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
| Abstract: | Cellulosic aerogels have attracted much attention because of their low density, high porosity and low thermal conductivity in many modified composite materials. Glycidyl methacrylate (GMA) is a new type of polymeric monomer with low cost, low toxicity, good biocompatibility, and easy chemical modification that has emerged in recent years, and it was widely used in the modification of rubber, fiber and other polymer materials. Cellulose composite aerogel, which is constructed by using GMA as a bridge to connect other materials, has rich functionality and shows great application potential in biomedicine, catalysis, adsorption and other fields. In this paper, the classification and properties of aerogels and cellulose are briefly described at first, then the synthesis methods of cellulose aerogels are introduced, and the applications of composite aerogels synthesized from cellulose modified by GMA in various fields in recent years are reviewed. This paper reviews the application of GMA-modified cellulose composite aerogels about the heavy metal and dye adsorption, biological tissues, wound dressings, drug carriers, biosensor and catalytic carriers. Finally, the future development prospect and current limitations of GMA modified cellulose aerogel are briefly introduced. |
| Keywords: | Cellulosic; Aerogels; Glyceride Methacrylate; Application |
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